SMART EDUCATIONS 1
ATOMS AND MOLECULES
Q. What is an atom?
Ans. Atoms are the building block or structural unit of matter.
Q. What is a molecule?
Ans. Molecule is the smallest part of a matter which shows all the
properties of the matter. Two or more atoms chemically combine to form
molecules.
Q. Who used the term atom for the first time?
Ans. The Greek philosopher Democritus who coined the term "atom" for
the first time from the Greek word atomos, which means "indivisible".
The Indian sage and philosopher Acharya Kanad or Maharishi Kanad
is credited with first proposing the idea of atoms(Parmanu) in India:
Q. How big are atoms?
Ans. An atom is so small that we can’t imagine or compare it with anything.
So, it can’t be seen with naked eyes. Size of the atomic radius is measured
in nanometers(nm). 1nm = 10
-9
m. The smallest atom is helium and the
largest atom is francium.
Q. How do atoms exist?
Ans. An Indian philosopher Pakudha Katyayama said that atoms normally
exist in a combined form which gives us various forms of matter.
Most of the atoms of elements are found in the form of molecules or
ions.
Q. Who gave the atomic theory?
Ans. The atomic theory was given by an English scientist John Dalton in
1808.
Q. Write Dalton’s atomic theory.
SMART EDUCATIONS 2
Ans. According to Dalton’s atomic theory, all matter, whether an element, a
compound or a mixture is composed of small particles called atoms. The
postulates of this theory may be stated as follows:
1. All matter is made of very tiny particles called atoms, which
participate in chemical reactions.
2. Atoms are indivisible particles, which cannot be created or destroyed
in a chemical reaction.
3. Atoms of a given element are identical in mass and chemical
properties.
4. Atoms of different elements have different masses and chemical
properties.
5. Atoms combine in the ratio of small whole numbers to form
compounds.
6. The relative number and kinds of atoms are constant in a given
compound.
Q. What are the drawbacks of Dalton’s atomic theory?
Ans. Dalton’s atomic theory has some drawbacks and they are:-
1. According to him, atoms are indivisible, but later it was found that
atoms are made up of subatomic particles.
2. According to him, atoms of a given element are identical in mass but
the discovery of Isotopes makes him wrong, which says that atoms of
a given element may not be identical in mass like some hydrogen’s
atomic mass has 1u some has 2u and some has 3u.
3. According to him, atoms of different elements have different masses
but the discovery of Isobars makes him wrong, which says that atoms
of different elements may have different masses like Calcium and
Potassium both have mass 40u.
Q. Who gave the laws of chemical combination?
Ans. The laws of chemical combination were given by Antoine L.
Lavoisier.
Q. What are the laws of chemical combination?
Ans. There are two laws of chemical combination:-
SMART EDUCATIONS 3
1. Law of conservation of mass, given by Antoine L. Lavoisier.
2. Law of constant proportions, given by Joseph L. Proust.
Q. State the Law of conservation of mass.
Ans. Law of conservation of mass states that “Mass can neither be created
nor destroyed in a chemical reaction.”
Q. State the Law of constant proportions.
Ans. Law of constant proportions states that “In a chemical substance the
elements are always present in definite proportions by mass.”
Q. What does IUPAC stand for?
Ans. IUPAC stands for “International Union of Pure and Applied
Chemistry”. It is an independent worldwide scientific organization.
Q. What are the functions of IUPAC?
Ans. IUPAC approves names of elements, their symbols and their mass
unit.
Q. How do all elements get their names?
Ans. Elements have been named after a number of things including :-
1. The name of the place where they were found for the first time. For
example, the name coppe r was taken from Cyprus .
2. Specific colours, For example, gold was taken from the English word
meaning yellow.
Q. Who starts the symbolisation of an element?
Ans. Dalton was the first scientist to use the symbols for elements in a very
specific sense but it was difficult to use and memorise, then, Berzilius
suggested that the symbols of elements be made from one or two letters of
the name of the element. So Berzilius is credited for the symbolisation of an
element.
Q. What are the rules used by IUPAC to assign a symbol to an element?
Ans. The rules used by IUPAC to assign a symbol to an element are:-
SMART EDUCATIONS 4
1. Many of the symbols are the first one or two letters of the element’s
name in English.
2. The first letter of a symbol is always written as a capital letter and the
second letter as a small letter
3. Some symbols have been taken from the names of elements in Latin,
German or Greek.
Q. Table of the symbols of elements.
Ans.
Q. Give some examples of elements whose symbols have been made from
Latin names.
Ans. Some examples of them are:-
1. Gold has the symbol Au, derived from its latin name which is Aurum .
2. Silver has the symbol Ag, derived from its latin name which is
Argentium .
3. Iron has the symbol Fe, derived from its latin name which is Ferrum .
4. Sodium has the symbol Na, derived from its latin name which is
Natrium .
5. Potassium has the symbol K, derived from its latin name which is
Kalium .
Q. Name the first scientist who talked about the atomic mass.
Ans. John Dalton was the first scientist who talked about the atomic mass
in his atomic theory.
SMART EDUCATIONS 5
Q. How were the atomic masses calculated?
Ans. Since determining the mass of an individual atom was a relatively
difficult task, relative atomic masses were determined using the laws of
chemical combinations and the compounds formed. For this, in 1961 1/12
th
part of an atom of carbon-12 isotope was selected by IUPAC, before it was
1/16
th
part of an atom of oxygen.
Q. What is relative atomic mass?
Ans. The relative atomic mass of the atom of an element is defined as the
average mass of the atom, as compared to 1/12
th
the mass of one
carbon-12 atom.
The relative atomic masses of all elements have been found with
respect to an atom of carbon-12.
Q. Define the atomic mass unit.
Ans. One atomic mass unit is a mass unit equal to exactly one-twelfth
(1/12
th
) the mass of one atom of carbon-12. The SI unit of atomic mass is
“unified mass” which is denoted as “u”.
Q. Define 1 unified mass.
Ans. 1 unified mass is equal to the mass of one-twelfth the mass of one
atom of carbon-12.
Q. Write atomic masses of some elements.
Ans.
SMART EDUCATIONS 6
Q. What is a molecule?
Ans. A molecule is in general a group of two or more atoms that are
chemically bonded together. It is the smallest particle of an element or a
compound that is capable of an independent existence and shows all the
properties of that substance.
Q. How many types of molecules are there?
Ans. There are two types of molecules:-
1. Molecules of elements: - The molecules of an element are constituted
by the same type of atoms. For example:- H
2
, Cl
2
, N
2
, O
2
, O
3
, P
4
,
S
8
, Al, He, Ne, Ar etc.
2. Molecules of compounds:- Atoms of different elements join together
in definite proportions to form molecules of compounds. For example
:- CO
2
, H
2
O , NH
3
, NH
4
etc.
Q. What is atomicity?
Ans. The number of atoms constituting a molecule is known as its
atomicity. For example:- Atomicity of H
2
= 2, O
3
= 3, P
4
= 4, S
8
=8, H
2
O = 3,
NH
3
= 4, NH
4
= 5 etc.
Q. What does monatomic mean?
Ans. The molecules of an element which are constituted by 1 atom. All
noble gases(He, Ne, Ar, etc) and all metals(Al, Mg, Ca, Fe, Cu, etc.)
SMART EDUCATIONS 7
Q. What does diatomic mean?
Ans. The molecules of an element or compound which are constituted by 2
atoms. For example:- H
2
, Cl
2
, N
2
, O
2
, CO, NaCl etc.
Q. What does triatomic mean?
Ans. The molecules of an element or compound which are constituted by 3
atoms. For example:- O
3
, H
2
O etc.
Q. What does tetratomic mean?
Ans. The molecules of an element or compound which are constituted by 4
atoms. For example:- P
4
, NH
3
CO
3
, etc.
Q. What does polyatomic mean?
Ans. All the molecules of an element or compound which are constituted
by more than 2 atoms. For example:- H
2
, O
3
, P
4
, S
8
, NH
3
CO
3
, etc.
Q. What are the differences between atoms and molecules?
Ans.
Atoms
Molecules
They are the smallest particle of a
matter that may or may not show
the properties of the matter.
They are the smallest particle of a
matter that must show all properties
of the matter.
They are not stable.
They are stable.
They may or may not exist
independently.
They exist independently.
Atoms are made up of subatomic
particles
Molecules are made up of atoms.
Example of atoms:- H,P,S,Cl etc.
(Atom of hydrogen = H)
Example of molecules:- H
2
,P
4
,S
8
etc. (Molecules of of hydrogen = H
2
)
SMART EDUCATIONS 8
Q. What is an ion?
Ans. The charged particles in a molecule are called ions. There are two
types of ions:-
1. Cation:- Positive charge is called cation. Examples of cations(all
metals) are:- Al
3+
,Ca
2+
,Na
+
etc.
2. Anion:- Negative charge is called anion. Examples of anions(almost
all non metals) are :- O
2-
, H
-
,S
2-
etc.
Q. What does polyatomic ion mean?
Ans. A group of atoms carrying a charge is known as a polyatomic ion. For
example:- SO
4
2-
, CO
3
2-
, OH
-
etc.
Q. Names and symbols of some ions.
Q. What does chemical formula mean?
Ans. The chemical formula of a compound is a symbolic representation of
its composition. For example chemical formula of water = H
2
O which
represents that the compositions of water are Hydrogen and Oxygen.
Examples of some chemical formulas:-
SMART EDUCATIONS 9
Common Name
Chemical Name
Chemical Formula
Quick lime
Calcium Oxide
CaO
Slaked lime
Calcium Hydroxide
Ca(OH)
2
Limestone
Calcium Carbonate
CaCO
3
Blue Vitriol
Copper Sulphate Pentahydrate
CuSO
4
.5H
2
O
Green Vitriol
Ferrous Sulphate Heptahydrate
FeSO
4
.7H
2
O
Baking Soda
Sodium Hydrogen Carbonate
NaHCO
3
Sulphuric Acid
Hydrogen Sulphate
H
2
SO
4
Nitric Acid
Hydrogen Nitrate
HNO
3
Hydrochloric Acid
Hydrogen Chloride
HCl
Water
Hydrogen Oxide
H
2
O
Milk of Magnesia
Magnesium Hydroxide
Mg(OH)
2
Caustic Soda
Sodium Hydroxide
NaOH
Common Salt
Sodium Chloride
NaCl
Ammonia
Nitrogen Trihydride
NH
3
Ammonia
Nitrogen Tetrahydride
NH
4
Q. What does valency mean?
Ans. The combining power of an element is known as the valency of an
atom. For example valency of Al is 3(Al
3+
), valency of O is 2(O
2-
), valency of
Na is 1(Na
+
) etc.
Q. Find the atomicity of Aluminium Sulphate.
Ans. Aluminium Sulphate = Al
2
(SO
4
)
3
So, in Aluminium Sulphate the number of Aluminium atoms = 2
the number of Sulphur atoms = 1 3= 3
×
the number of Oxygen atoms = 4 3= 12
×
SMART EDUCATIONS 10
So, the atomicity of Aluminium Sulphate is = 2+3+12
= 17
Q. Find the molecular mass of Aluminium Sulphate.
Ans. Aluminium Sulphate = Al
2
(SO
4
)
3
So, in Aluminium Sulphate the mass of Aluminium atoms = 2 27 = 54u
×
the mass of Sulphur atoms = 1 3 32= 96u
× ×
the mass of Oxygen atoms = 4 3 16= 192u
× ×
So, the molecular mass of Aluminium Sulphate = 54+96+192
= 342u
Q. Calculate the relative molecular mass of water (H
2
O).
Ans. H
2
O = 2 H + 1 O
× ×
= 2 1 + 1 16
× ×
= 2 + 16
= 18 u Ans
Q. Calculate the molecular mass of HNO
3
.
Ans. HNO
3
= 1 H + 1 N + 3 O
× × ×
= 1 1 + 1 14 + 3 16
× × ×
= 1 + 14 + 48
= 63 u Ans
Q. Find the mass ratio of Hydrogen and Oxygen in water.
Ans. Water = H
2
O
Mass of Hydrogen in water = 2 1= 2 ×
Mass of oxygen in water = 1 16 = 16
×
The mass ratio of Hydrogen and Oxygen in water =
2
16
=
1
8
= 1 : 8
Q. Find the atomic ratio of Hydrogen and Oxygen in water.
Ans. Water = H
2
O
Mass of Hydrogen in water = 2
Mass of oxygen in water = 1
SMART EDUCATIONS 11
The mass ratio of Hydrogen and Oxygen in water =
2
1
= 2 : 1
Q. Write down the formulae of
1. sodium oxide
Ans. Na
2
O
2. aluminium chloride
Ans. AlCl
3
3. sodium suphide
Ans. Na
2
S
4. magnesium hydroxide
Ans. Mg(OH)
2
2. Write down the names of compounds represented by the following
formulae:
(i) Al
2
(SO
4
)
3
Ans. Aluminium Sulphate
(ii) CaCl
2
Ans. Calcium Chloride
(iii) K
2
SO
4
Ans. Potassium Sulphate
(iv) KNO
3
Ans. Potassium Nitrate
(v) CaCO
3
Ans. Calcium Carbonate
Q. Calculate the molecular masses of H
2
, O
2
, Cl
2
, CO
2
, CH
4
, C
2
H
6
, C
2
H
4
,
NH
3
, CH
3
OH
Ans. H
2
= 2 H O
2
= 2 O Cl
2
= 2 Cl
× × ×
= 2 1 = 2 16 = 2 35.5
× × ×
= 2 u Ans = 32 u Ans = 71 u Ans
CO
2
= 1 C + 2 O CH
4
= 1 C + 4 H C
2
H
6
= 2 C + 6 H
× × × × × ×
= 1 12 + 2 16 = 1 12 + 4 1 = 2 12 + 6 1
× × × × × ×
= 12 + 32 = 12 + 4 = 24 + 6
= 44 u Ans = 16 u Ans = 30 u Ans
SMART EDUCATIONS 12
C
2
H
4
=2 C + 4 H NH
3
=1 N + 3 H CH
3
OH = 1 C + 4 H + 1 O
× × × × × × ×
= 2 12 + 4 1 =1 14 + 3 1 =1 12 + 4 1 +1 16
× × × × × × ×
= 24 + 4 = 14 + 3 = 12 + 4 + 16
= 28 u Ans = 17 u Ans =32 u Ans
Q. Calculate the formula unit masses of ZnO, Na
2
O, K
2
CO
3
, given atomic
masses of Zn = 65 u, Na = 23 u, K = 39 u, C = 12 u, and O = 16 u.
Ans.
ZnO = 1 Zn + 1 O , Na
2
O = 2 Na + 1 O , K
2
CO
3
= 2 K + 1 C+ 3 O
× × × × × × ×
= 1 65 + 1 16 = 2 23 + 1 16 =2 39 +1 12 +3 16
× × × × × × ×
= 65 + 16 = 46 + 16 = 78 + 12 + 48
= 81 u Ans = 62 u Ans = 138 u Ans
Q. Calculate the formula unit mass of CaCl
2
.
Ans. CaCl
2
= 1 Ca + 2 Cl
× ×
= 1 40 + 2 35.5
× ×
= 40 + 71
= 111 u Ans
Q. Write the atomic mass of oxygen and molecular mass of oxygen.
Ans. Atom of oxygen means = O and
Molecule of oxygen means = O
2
So, the atomic mass of oxygen = 1 16
×
= 16 u Ans
Molecular mass of oxygen = 2 16 ×
= 32 u Ans
Exercise
1. A 0.24 g sample of a compound of oxygen and boron was found by
analysis to contain 0.096 g of boron and 0.144 g of oxygen. Calculate
the percentage composition of the compound by weight.
Ans. Boron = 0.096 g
Oxygen = 0.144 g
SMART EDUCATIONS 13
Total = 0.24 g
Boron% = ?
Oxygen% = ?
𝐵𝑜𝑟𝑜𝑛 % =
𝐵𝑜𝑟𝑜𝑛
𝑇𝑜𝑡𝑎𝑙
× 100 𝑂𝑥𝑦𝑔𝑒𝑛 % =
𝑂𝑥𝑦𝑔𝑒𝑛
𝑇𝑜𝑡𝑎𝑙
× 100
=
0 . 096
0 . 24
× 100 =
0 . 144
0 . 24
× 100
Ans Ans
= 40% = 60%
2. When 3.0 g of carbon is burnt in 8.00 g oxygen, 11.00 g of carbon
dioxide is produced. What mass of carbon dioxide will be formed
when 3.00 g of carbon is burnt in 50.00 g of oxygen? Which law of
chemical combination will govern your answer?
Ans. Because 3.0 g of carbon is burnt in 8.00 g oxygen, 11.00 g of carbon
dioxide is produced.
So, when 3.00 g of carbon is burnt in 50.00 g of oxygen then
according to the law of constant proportion:- 3.00 g of carbon will
burn in 8.00 g of oxygen to produce 11.00g of carbon dioxide and
42.00 g of oxygen will be left.
So, 11.00g of carbon dioxide will form. Law of constant proportion
governs my answer.
3. What are polyatomic ions? Give examples.
Ans. A group of atoms carrying a charge is known as a polyatomic ion. For
example:- SO
4
2-
, CO
3
2-
, OH
-
etc.
4. Write the chemical formulae of the following.
a. Magnesium chloride
Ans. MgCl
2
b. Calcium oxide
Ans. CaO
c. Copper nitrate
Ans. CuNO
3
d. Aluminium chloride
Ans. AlCl
3
e. Calcium carbonate.
SMART EDUCATIONS 14
Ans. CaCO
3
5. Give the names of the elements present in the following compounds.
a. Quick lime
Ans. Formula of Quick lime = Cao
So, in Quick lime, Calcium and Oxygen elements are
present.
b. Hydrogen bromide
Ans. Formula of Hydrogen bromide = HBr
So, in Hydrogen bromide, Hydrogen and Bromine
elements are present.
c. Baking powder
Ans. Formula of Baking powder = NaHCO
3
So, in Baking powder, Sodium, Hydrogen, Carbon and
Oxygen elements are present.
d. Potassium sulphate.
Ans. Formula of Potassium sulphate = K
2
SO
4
So, in Potassium sulphate, Potassium, Sulphur and
Oxygen elements are present.
6. Calculate the molecular mass of the following substances.
a. Ethyne, C
2
H
2
Ans. C
2
H
2
= 2 C + 2 H
× ×
= 2 12 + 2 1
× ×
= 24 + 2
= 26 u Ans
b. Sulphur molecule, S
8
Ans. S
8
= 8 S
×
= 8 32
×
= 256 u Ans
SMART EDUCATIONS 15
c. Phosphorus molecule, P
4
(Atomic mass of phosphorus= 31)
Ans. P
4
= 4 P
×
= 4 31
×
= 124 u Ans
d. Hydrochloric acid, HCl
Ans. HCl = 1 H + 1 Cl
× ×
= 1 1 + 1 +35.5
×
= 1 + 35.5
= 36.5 u Ans
e. Nitric acid, HNO
3
Ans. HNO
3
= 1 H + 1 N + 3 O
× × ×
= 1 1 + 1 14 + 3 16
× × ×
= 1 + 14 + 48
= 63 u Ans